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Studies of the cis-trans isomerism of some square-planar platinum(II) nitroimidazole complexes

✍ Scribed by Fiona M. MacDonald; Peter J. Sadler

Book ID
108428318
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
585 KB
Volume
10
Category
Article
ISSN
0277-5387

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The trans effect in square-planar platin
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## Abstract The mechanism of substitution water exchange reactions in square planar trans‐Pt[(NH~3~)~2~T(H~2~O)]^n+^ complexes is studied (Tο£ΎH~2~O, NH~3~, OH^βˆ’^, F^βˆ’^, Cl^βˆ’^, Br^βˆ’^, H~2~S, CH~3~S^βˆ’^, SCN^βˆ’^, CN^βˆ’^, PH~3~, CO, CH~3~^βˆ’^, H^βˆ’^, C~2~H~4~). The trans effect is explained in terms of σ‐do