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A method for rhodium(II)-catalyzed aziridination of olefins

✍ Scribed by Paul Müller; Corine Baud; Yvan Jacquier


Book ID
103402765
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
554 KB
Volume
52
Category
Article
ISSN
0040-4020

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✍ Jiang-Lin Liang; Shi-Xue Yuan; Philip Wai Hong Chan; Chi-Ming Che 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 114 KB

The asymmetric intramolecular aziridination of unsaturated sulfonamides and carbamates catalyzed by chiral dirhodium(II,II) complexes were achieved in good yields (up to 95%) and enantioselectivity (up to 76% e.e.).