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A method for computer analysis of kinetics of competing first- and second-order reactions

✍ Scribed by Donald S. Gorman; John S. Connolly

Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
644 KB
Volume
5
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

Competing first‐ and second‐order reactions of transient molecular species (e.g., triplet states and free radicals) are a common occurrence in kinetic studies such as flash photolysis and pulse radiolysis. We have developed a method for analyzing the decay kinetics of any species (Y) whose disappearance is described by βˆ’dY/dt = k~1~Y + k~2~Y^2^. The computer program (written in time‐sharing BASIC) employs an iterative technique to obtain the least‐squares estimates of the three parameters in the integrated rate equation.

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