A differential method for analyzing first-order kinetic data is presented. While the essence of this approach has been known for almost a century, the use of computers to collect, store, and manipulate data has reenergized this innovative idea. Based on the equation ln dA t /dt Ο ln k(A o Οͺ A Ο± ) Οͺ
Numerical analysis of kinetic data: Collapsed regression analysis for first order reactions
β Scribed by Michael H. Klapper
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 282 KB
- Volume
- 72
- Category
- Article
- ISSN
- 0003-2697
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π SIMILAR VOLUMES
The system of a sequence of five first-order reactions, A -B -C -D -E -F , has been analyzed kinetically. An actual example is proposed in the reaction of mesitonitrile in 89.8% (w/w) sulfuric acid a t 98.3OC. The analysis provides estimates of concentration ratios as functions of time, and the prog
Dibenzoylmesitylene undergoes protiodeacylation in 89.8% (w/w) sulfuric acid at ca. 9O"C, with subsequent sulfonation, to give mesitylenedisulfonic acid. The reaction involves a single-path sequence of four first-order reactions. The corresponding reaction of acetylbenzoylmesitylene can proceed by t