𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Kinetic analysis of a single-path, and of a dual-path, sequence of four first-order reactions. The reactions of dibenzoylmesitylene and acetylbenzoylmesitylene in sulfuric acid

✍ Scribed by Jameel A. Farooqi; Peter H. Gore; David N. Waters; Gerald F. Moxon

Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
311 KB
Volume
20
Category
Article
ISSN
0538-8066

No coin nor oath required. For personal study only.

✦ Synopsis

Dibenzoylmesitylene undergoes protiodeacylation in 89.8% (w/w) sulfuric acid at ca. 9O"C, with subsequent sulfonation, to give mesitylenedisulfonic acid. The reaction involves a single-path sequence of four first-order reactions. The corresponding reaction of acetylbenzoylmesitylene can proceed by two possible routes: it is shown that about 942 of the overall reaction a t 75" involves initial protiodeacetylation and about 6% initial protiodebenzoylation. The kinetic analyses provide estimates of concentration ratios as functions of time, and of the buildup and decay of intermediates in the reactions.

' t l for increasing R. ' t , for decreasing R.

📜 SIMILAR VOLUMES

Kinetic analysis of an extended single-p
Kinetic analysis of an extended single-path sequence of first-order reactions. The reaction of mesitonitrile in sulfuric acid
✍ Ja′far Al-ka′bi; Peter H. Gore; Esmat F. Saad; David N. Waters; Gerald F. Moxon 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 English ⚖ 277 KB

The system of a sequence of five first-order reactions, A -B -C -D -E -F , has been analyzed kinetically. An actual example is proposed in the reaction of mesitonitrile in 89.8% (w/w) sulfuric acid a t 98.3OC. The analysis provides estimates of concentration ratios as functions of time, and the prog

A dual-path sequence of first-order reac
A dual-path sequence of first-order reactions the protiodeacylation of acetylpropionylmesitylene
✍ Peter H. Gore; Ahmed M. G. Nassar; David N. Waters; Gerry F. Moxon 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 215 KB

## Abstract An example of a sequence of competing first‐order reactions, leading to a common product, has been found for the sulfodeacylation of acetylpropionylmesitylene. The basic reaction scheme is Scheme l equation image and a kinetic analysis of the component rate constants allows an estimate