The Raman optical activity (ROA) spectrum of ( + )-( 3R)-methylcyclohexanone from 150 to 1400 cm-' measured using a novel ROA spectrometer is reported. The spectrometer features a Soleil-Babinet compensator to produce high-quality circularly polarized laser radiation. The principal ROA couplets are
A method for calibration of Soleil-Babinet compensator using a spectrophotometer
β Scribed by Jun Wang; Lei Chen; Bo Li; Lili Shi; Ting Luo
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 423 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0143-8166
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β¦ Synopsis
A method using a spectrophotometer for calibrating Soleil-Babinet compensator is proposed. It is based on the spectroscopic method which utilizes the relation between transmittance and wavelength to obtain retardation. By placing a multiple order half wave plate behind the Soleil-Babinet compensator, zero-order retardation can be measured, which is difficult to accomplish by spectroscopic method. In the experiment, the retardations of the compensator in the range 0-l are measured. It is demonstrated that the precision of retardation is 0.45 nm at the position 0 and l while the maximum error is less than 1 nm between the two positions.
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