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A soleil-babinet compensator based Raman optical activity spectrometer: interpretation of roa couplets in (+)-(3R)-methylcyclohexanone

✍ Scribed by Carl G Zimba; Teresa B Freedman; Kevin M Spencer; Xiao-Ming Hu; Laurence A Nafie


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
469 KB
Volume
134
Category
Article
ISSN
0009-2614

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✦ Synopsis


The Raman optical activity (ROA) spectrum of ( + )-( 3R)-methylcyclohexanone from 150 to 1400 cm-' measured using a novel ROA spectrometer is reported. The spectrometer features a Soleil-Babinet compensator to produce high-quality circularly polarized laser radiation. The principal ROA couplets are assigned and interpreted in terms of pairs of coupled vibrational motions.