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A mechanistic study of the epoxidation of cinnamic acid by hydrogen peroxide catalysed by manganese l,4,7-trimethyl-l,4,7-triazacyclononane complexes

✍ Scribed by Bruce C Gilbert; John R Lindsay Smith; Antoni Mairata i Payeras; John Oakes; Roger Pons i Prats

Book ID
108211346
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
187 KB
Volume
219
Category
Article
ISSN
1381-1169

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πŸ“œ SIMILAR VOLUMES

Efficient stereoselective oxygenation of
Efficient stereoselective oxygenation of alkanes by peroxyacetic acid or hydrogen peroxide and acetic acid catalysed by a manganese(IV) 1,4,7-trimethyl-1,4,7-triazacyclononane complex
✍ John R. Lindsay Smith; Georgiy B. Shul'pin πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 233 KB

The dinuclear manganese complex [LMnrV(O)3MnVeL](PF6)2, where L is 1,4,7-trimethyl-l,4,7-triazacyclononane, catalyses the oxygenation ofalkanes by peroxyacetic acid or by H202 in the presence of acetic acid to give alkanols, alkanones and alkyl hydroperoxides. The reactions can give large turnovers

ChemInform Abstract: Efficient Stereosel
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Efficient Stereoselective Oxygenation of Alkanes by Peroxyacetic Acid or Hydrogen Peroxide and Acetic Acid Catalyzed by a Manganese( IV) 1,4,4,-The oxidation of unfunctionalized alkanes such as (I) is achieved by peroxyacetic acid (or H 2 O 2 /AcOH) in the presence of a dinuclear Mn(IV) complex as c