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Complexes of N,N′,N′′-tris(2-hydroxypropyl)-1,4,7-triazacyclononane (L): Structures of [CuL](ClO4)(NO3), [CoL](ClO4)2, [ZnL](ClO4)2and the catalytic activity of [MnL](ClO4)2towards olefin epoxidation with hydrogen peroxide

✍ Scribed by Xi-Mei Feng; Zhong Zhang; Yi-Zhi Li; Ning-Sheng Bian; Zhi-Lin Wang


Publisher
Springer
Year
2007
Tongue
English
Weight
438 KB
Volume
32
Category
Article
ISSN
0340-4285

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✍ Zhi-Hui Zhang; Hai-Long Yang; Zhi-Hong Ma; Ai-Di Qi 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 434 KB 👁 2 views

## Abstract Two monomeric cobalt(II) complexes, [CoL(N~3~)]ClO~4~ (1) and CoL(N~3~)~2~ (2), where L is tris((3,5‐dimethylpyrazol‐yl) methyl) amine, were synthesized and their crystal structures were determined by X‐ray diffraction technique. Complex 1 is five coordinated with one azide nitrogen ato