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A many-particle treatment of the reversible reaction A+B⇔C+B

✍ Scribed by Gopich, I. V.; Kipriyanov, A. A.; Doktorov, A. B.

Book ID
121085319
Publisher
American Institute of Physics
Year
1999
Tongue
English
Weight
571 KB
Volume
110
Category
Article
ISSN
0021-9606

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A many-particle derivation of non-Markov
A many-particle derivation of non-Markovian kinetic equations of reversible reaction A+B⇌C in solutions based on the effective pairs approach
✍ A.A. Kipriyanov; A.B. Doktorov 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 350 KB

The non-Markovian kinetic equations for local concentrations have been derived in the e ective pairs approximation on the basis of the hierarchy for correlation patterns of the reversible reaction A + B C. The equations are shown to agree with the kinetic and thermodynamic detailed balancing princip