The synthetic and structural organometallic chemistry of manganese(ii) is atypical of organotransition metal chemistry due to the observation of essentially ionic CÀMn II bonds, a property more commonly observed in organometallic compounds of the alkali and alkaline-earth metals. [1] Hence Mn II for
A Manganese(II) Allyl Complex: Synthesis, Structure, and Magnetic Properties of [Li(thf)4][Mn{η3-(Me3Si)2C3H3}{η1-(Me3Si)2C3H3}2]
✍ Scribed by Richard A. Layfield; Simon M. Humphrey
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 106 KB
- Volume
- 116
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
N bzw. C zu N an. Analoge Umsetzungen gelangen mit den Lithiumsilyl-(und -germyl-)Kongeneren von LiCR 3 . So ergaben [Li(SiR 3 )(thf) 3 ] und 2,6-Me 2 C 6 H 3 CN (ArCN) in einer Reaktionsfolge, die eine bis dahin unbekannte Me 3 Si-Verschiebung von Si zu N einschloû, den zwitterionischen 3-Sila-b-di
Recently we reported on the synthesis of the C 2 -symmetric trans-rac-ansa-lanthanoacenes [1] [(h 5 -C 12 H 8 ) 2 M(thf) 2 ] (M Yb, 1; Sm, 2) by reductive coupling of acenaphthylene (acene) with activated metallic ytterbium or samarium. [2] The acenyl radical anions formed in the course of these red