A light-harvesting array of synthetic porphyrins
β Scribed by Jorge Davila; Anthony Harriman; Lionel R. Milgrom
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 417 KB
- Volume
- 136
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
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## Abstract We have demonstrated the construction of multiple porphyrin arrays in the tobacco mosaic virus (TMV) supramolecular structures by selfβassembly of recombinant TMV coat protein (TMVCP) monomers, in which Znβcoordinated porphyrin (ZnP) and freeβbase porphyrin (FbP) were siteβselectively i
Pentameric porphyrin hosts, in which a TPP type porphyrin was attached to four OEP type zinc porphyrins through a 1,3-phenylene spacer, were synthesized. Its spectroscopic investigations suggest that the host binds a one molecule of meso-tetrapyridyl porphyrin by coordination to the central metals o