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Supramolecular assembly of light harvesting porphyrin hexamer

✍ Scribed by Hideyuki Shinmori; Takashi Kajiwara; Atsuhiro Osuka

Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
97 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

Pentameric porphyrin hosts, in which a TPP type porphyrin was attached to four OEP type zinc porphyrins through a 1,3-phenylene spacer, were synthesized. Its spectroscopic investigations suggest that the host binds a one molecule of meso-tetrapyridyl porphyrin by coordination to the central metals of the peripheral four zinc porphyrins to constitute a light harvesting porphyrin hexameric assembly.

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