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Windmill-Like Porphyrin Arrays as Potent Light-Harvesting Antenna Complexes

โœ Scribed by Aiko Nakano; Atsuhiro Osuka; Iwao Yamazaki; Tomoko Yamazaki; Yoshinobu Nishimura


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
174 KB
Volume
37
Category
Article
ISSN
0044-8249

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ฯ€-Electronic conjugation is not necessary to facilitate long-range energy migration and transfer: A rapid (k =1.04ร—10 s ) and efficient (ฮฆ =71โ€‰%) energy transfer from the 28 photoexcited zinc porphyrin units to the focal free-base porphyrin unit occurs in a large, star-shaped dendritic multiporphyri