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A laser-photolysis/lif study of the rate constant for the reaction CH3O + O → products at 298 K

✍ Scribed by D. Rhäsa; R. Zellner

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
387 KB
Volume
132
Category
Article
ISSN
0009-2614

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✦ Synopsis

The kinetics of the reaction CH30 + 0 -+ products at 298 K has been investigated using laser-induced fluorescence (LIF) for the time-resolved detection of CHsO radicals. The rate constant kr is found to be (2.5 f 0.7) X lo-" cm3/s. The reaction is assumed to proceed by at least two different product channels, (a) CH3 + 02 and (b) CH20 + OH, with the yield of (b) being 20 f 10% of the total.

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