𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Rate constant and products of the BrO + BrO reaction at 298 K

✍ Scribed by I. T. Lançar; G. Laverdet; G. Le Bras; G. Poulet

Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
476 KB
Volume
23
Category
Article
ISSN
0538-8066

No coin nor oath required. For personal study only.

✦ Synopsis

The overall rate coefficient k of the self recombination of BrO radicals has been measured at 298 K with use of the discharge flow/mass spectrometry technique. The rate coefficient kz for the reaction channel forming Bra has been also determined. The results are: k = (3.2 2 0.5) X and kz = (4.7 t 1.5) x (in cm3 molecule-' s-'). These results are discussed with respect to previous literature data.

📜 SIMILAR VOLUMES

Kinetics of the reactions of CH3O with B
Kinetics of the reactions of CH3O with Br and BrO at 298 K
✍ Alfonso Aranda; Véronique Daële; Georges Le Bras; Gilles Poulet 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 142 KB 👁 2 views

A discharge flow reactor coupled to a laser-induced fluorescence (LIF) detector and a mass spectrometer was used to study the kinetics of the reactions CH O ϩ Br : 3 (1) and (2). From the kinetic analysis of CH 3 O by LIF in the products CH O ϩ BrO : products 3 presence of an excess of Br or BrO, th

Rate constants for the reactions of chlo
Rate constants for the reactions of chlorine atoms with hydrochloroethers at 298 k and atmospheric pressure
✍ Pablo R. Dalmasso; Raúl A. Taccone; Jorge D. Nieto; Mariano A. Teruel; Silvia I. 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 142 KB 👁 1 views

## Abstract The relative rate technique has been used to determine the rate constants for the reactions Cl + CH~3~OCHCl~2~ → products and Cl + CH~3~OCH~2~CH~2~Cl → products. Experiments were carried out at 298 ± 2 K and atmospheric pressure using nitrogen as the bath gas. The decay rates of the org

Rate constant and RRKM product study for
Rate constant and RRKM product study for the reaction between CH3 and C2H3 at T = 298 K
✍ R. Peyton Thorn; Jr.; Walter A. Payne; Jr.; Xavier D. F. Chillier; Louis J. Stie 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 165 KB 👁 2 views

The total rate constant k 1 has been determined at P ϭ 1 Torr nominal pressure (He) and at T ϭ 298 K for the vinyl-methyl cross-radical reaction: (1) CH 3 ϩ C 2 H 3 : Products. The measurements were performed in a discharge flow system coupled with collision-free sampling to a mass spectrometer oper

Rate constants for the reactions of mole
Rate constants for the reactions of molecular iodine with Cl, SiCl3, and SiH3 at 298 K
✍ A. V. Baklanov; E. N. Chesnokov; A. I. Chichinin 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 152 KB 👁 2 views

The angular and velocity distribution of the ICl product from reaction (1) at 4.5 kcal/mol collision energy has been obtained by Cross and Blais in a crossed-molecular-beam study [1]. It was concluded that the angular distribution is consistent with that arising from short range attractive forces an

Rate constant of the α-pinene + atomic h
Rate constant of the α-pinene + atomic hydrogen reaction at 295 K
✍ C. Vinckier; N. Van Hoof 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 454 KB

## Abstract The rate constant of the reaction of α‐pinene with atomic hydrogen was determined at 295 K using the fast‐flow reactor technique directly coupled to a mass spectrometric detection technique. The value was found to be equal to (9.8 ± 3.3) × 10^−13^ cm^3^ molecules^−1^ s^−1^ and independe