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A laser induced fluorescence study of vibrational energy transfer in dideuteromethane

✍ Scribed by V.A. Apkarian; Eric Weitz

Publisher: Elsevier Science
Year: 1978
Tongue: English
Weight: 521 KB
Volume: 59
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(78)85009-x

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✦ Synopsis

V-V and V-T/R rates of ~1, g , ~3, "6, ~8, and vg of CHz Dz were measured and are reported_ The deactivation efticiencies of rare gas coiIisian partners were measured and calculated by SSH theory, the results are reported ar.d discussed_ Possible V-V pathways are presented and discussed. * CHH, has dipo!e non-allowed transitions nameIy Al *Al and -41 +N E. Therefore any diople non-allowed V-V step would involve or, e.g. y1 ++ v-, 1 but since ~1 to ground is also infrared non&owed, its behavior has not been dire&y investigated.

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