Ir-laser-induced changes in the uv absorption spectrum of ozone. A new technique for vibrational energy-transfer studies

✍ Scribed by I.C. McDade; W.D. McGrath

• Publisher: Elsevier Science
• Year: 1980
• Tongue: English
• Weight: 393 KB
• Volume: 72
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(80)80324-1

✦ Synopsis

Reccn~d 31 \larch 1980 Gaseous ozone has been \lbratlonaU) evared usmp-smglc pulses from an IR laser oprratmg on the 9 5 pm band ofCO2 and trxtstcnt changes m UV absorption m the rcgon ot the Ilartlry continuum have been obscrwd These changes have been tcmporall> rcsol\ed at 310 nm m pure 03 and m binary ml\turcs of 03 wth Hc. Xr, Xc, Hz_ N2.02. CO2 and SFe, and rdtr. constants for the de-1 ot transwnt clbsorptlon obtamrd These rdt2 constants are compared atth those measured fur dc.wtwauon oirlbratlon.dl) culted O3 usmg IR ewltcd fluorescence and IR-enhanced ructlon techmques