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A large series of isotypic Mo(V) diphosphates with a tunnel structure: From A(MoO)10(P2O7)8 with A=Ba, Sr, Ca, Cd, Pb to A(MoO)5(P2O7)4 with A=Ag, Li, Na, K

✍ Scribed by André Leclaire; Vincent Caignaert; Bernard Raveau

Book ID
108195523
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
852 KB
Volume
180
Category
Article
ISSN
0022-4596

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📜 SIMILAR VOLUMES

Mo(V) Phosphates with an Opened Framewor
Mo(V) Phosphates with an Opened Framework: Li4−xA+x(MoO)3(PO4)3P2O7(A=Na, Ag, Cs, K), Li4−xBa2+x/2(MoO)3(PO4)3P2O7
✍ S. Ledain; A. Leclaire; M.M. Borel; M. Hervieu; J. Provost; B. Raveau 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 514 KB

The exploration of Li+A+Mo+P+O systems has allowed several Mo(V) phosphates, Li 4؊x A x (MoO) 3 (PO 4 ) 3 P 2 O 7 (A ‫؍‬ Na, Ag, Cs, K) and Li 3 Ba 0.5 (MoO) 3 (PO 4 ) 3 P 2 O 7 , to be synthesized. Two types of closely related structures are evidenced depending on the nature and content of the A ca

Rapid and Simple Isolation of the Crysta
Rapid and Simple Isolation of the Crystalline Molybdenum-Blue Compounds with Discrete and Linked Nanosized Ring-Shaped Anions: Na15[Mo3.0.CO;2-%23/asset/equation/tex2gif-stack-1.gif?v=1&t=h5l566t6&s=c0a09f77518ccacb50e822358608409f8e1c0a41" class="inlineGraphic">Mo3.0.CO;2-%23/asset/equation/tex2gif-stack-2.gif?v=1&t=h5l566t6&s=3b4dd445e7e4356504ec58daf107b378c9736f7b" class="inlineGraphic">O462H14(H2O)70]0.5 [Mo3.0.CO;2-%23/asset/equation/tex2gif-stack-3.gif?v=1&t=h5l566t6&s=32c4cd6315aa03537e50d3683e9830279c928f78" class="inlineGraphic">Mo3.0.CO;2-%23/asset/equation/tex2gif-stack-4.gif?v=1&t=h5l566t7&s=3a1388422ef00ab21b32f2e8ba73a564490bf0c1" class="inlineGraphic">O457H14(H2O)68]0.5 · ca. 400 H2O and Na22[Mo3.0.CO;2-%23/asset/equation/tex2gif-stack-5.gif?v=1&t=h5l566t7&s=2f041805f3359c66af741d31ef3916871c113c35" class="inlineGraphic">Mo3.0.CO;2-%23/asset/equation/tex2gif-stack-6.gif?v=1&t=h5l566t7&s=e3f6eced1d8e1eea086310b68afe457fcdf2951e" class="inlineGraphic">O442H14(H2O)58] · ca. 250 H2O
✍ Achim Müller; Samar K. Das; Vladimir P. Fedin; Erich Krickemeyer; Christian Beug 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 167 KB 👁 3 views

The blue mixed-crystal title compound Na 15 [Mo VI 126 Mo V 28 O 462 H 14 (H 2 O) 70 ] 0.5 [Mo VI 124 Mo V 28 O 457 H 14 (H 2 O) 68 ] 0.5 ´ca. 400 H 2 O º Na 15 [1 a] 0.5 [1 b] 0.5 ´ca. 400 H 2 O 1, which crystallizes in the triclinic space group P 1 (a = 30.785(2), b = 32.958(2), c = 47.318(3) A Ê