A flash photolysis resonance fluorescence technique has been employed to investigate the kinetics and mechanism of the reaction of OH(X 2 ) radicals with CH 3 I over the temperature and pressure ranges 295-390 K and 82-303 Torr of He, respectively. The experiments involved time-resolved RF detection
A kinetic study of the reaction of OH with olefins
โ Scribed by W.S. Nip; G. Paraskevopoulos
- Publisher
- Elsevier Science
- Year
- 1978
- Weight
- 137 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0047-2670
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Absolute rate coefficients for the reaction of OH with HCl (k,) have been measured as a function of temperature over the range 240-1055 K. OH was produced by flash photolysis of HzO at A > 165 nm, 266 nm laser photolysis of O3/HZO mixtures, or 266 nm laser photolysis of HzOZ. OH was monitored by tim
The rate coefficients for the reactions of OH with ethane ( k l ) , propane (kz), n-butane (k3), iso-butane (k4), and n-pentane ( k 5 ) have been measured over the temperature range 212-380 Kusing the pulsed photolysislaser induced fluorescence (PP-LIF) technique. The 298 Kvalues are (2.43 2 0.20) X
The rate constant of the reaction OH + HCI+ Hz0 + Cl was measured in a flow tube over the temperature range 224 to 460ยฐK using resonance fluorescence detection of OH. An Arrheaius expression ki = (2.0 f 0.1) X lo-'\* exp [ -(620 f 20 cal/mole)/RT] ws obtained. Stratospheric and reaction kinetic impl
Rate coefficients have been measured at 298 ฯฎ 4 K and 1000 mbar total pressure for the reactions of OH with a series of symmetrical acetals (R9O 9CH 2 9O 9R, R ฯญ C 1 to C 4 ) using a relative kinetic technique. The investigations have been performed in a laboratory photoreactor and also in the large