Kinetics and mechanism of the acid-catal
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Eleonora Danilczuk; Janusz ChatΕas
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Article
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1996
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Springer
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English
β 431 KB
The kinetics of the acid-catalysed hydrolysis of the [(imidazole)4Co(CO3) ] + ion was found to follow the rate law -dln[complex]/dt = k~K[H+]/(1 + K[H+]) in the 25-45 ~ range, [H +] 0.05-1.0 M range and I = 1.0 M. The reaction sequence consists of a rapid protonation equilibrium followed by the one-