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A Kinetic and Mechanistic Study of the Amino Acid Catalyzed Aldol Condensation of Acetaldehyde in Aqueous and Salt Solutions

✍ Scribed by Nozière, Barbara; Córdova, Armando


Book ID
120626946
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
361 KB
Volume
112
Category
Article
ISSN
1089-5639

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The rates of zinc incorporation, zinc demetallkon, and cupric ion displacement of zinc in a water-solubie porphyrin were investigated. The tetra-sulfonated tetraphenyiporphine TPPS (see Fig. 1) n-as employed in the studies. The rate of zinc ion incorporation was equal to [k,][Zn2+] EPPS J where kr =