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A Hofmann pyridine complex: poly[tetra-μ-cyano-dipyridine­manganese(II)nickel(II)]

✍ Scribed by Hosoya, Kazumasa ;Sekiya, Ryo ;Nishikiori, Shin-ichi

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
173 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [MnNi(CN)~4~(C~5~H~5~N)~2~], has a layered structure of a two-dimensional network complex Mn(py)~2~Ni(CN)~4~, in which linkages of cyanide between the equatorial coordination sites of octahedral Mn^II^ ions (site symmetry 2/m) and those of square planar Ni^II^ ions (site symmetry 2/m) form a square mesh network. Pyridine ligands (located on mirror planes) coordinate to the axial sites of the Mn^II^ ions from both sides of the network.

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