The title method is based on the recently discovered radical fragmentation of 2-fluoro-6-pyridinoxy derivatives of vinylsulfones. The radical addition of xanthates to these alkenes leads to the formation of (E)-vinylsulfone adducts, which are desulfonylated by treatment with sodium dithionite and so
A Highly Stereoselective, Modular Route to ( E )-Vinylsulfones and to ( Z )- and ( E )-Alkenes
✍ Scribed by Braun, Marie-Gabrielle; Quiclet-Sire, Béatrice; Zard, Samir Z.
- Book ID
- 120231172
- Publisher
- American Chemical Society
- Year
- 2011
- Tongue
- English
- Weight
- 933 KB
- Volume
- 133
- Category
- Article
- ISSN
- 0002-7863
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