Silver(I)-templated cyclocondensation of pyridine-2,6\_dicarbaldehyde and 3-oxa-1,5-diammopentane yields a dinuclear silver(I) complex of the '2+2' tetraimine Schiff base macrocycle L,. The crystal structure of the complex recrystallised from acetonitrile shows the product of recrystallisation to be
A Highly Stable Silver(I) Complex of a Macrocycle Derived from Tetraazatetrathiacyclen
✍ Scribed by Dipl.-Chem. Thomas Gyr; Prof. Dr. Helmut R. Mäcke; Dr. Michael Hennig
- Book ID
- 101558378
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 404 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0044-8249
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The syntheses of two new cyclophane hosts, 4 and 6, are described. The main difference between them is the higher degree of preorganization of 4 as a consequence of the inclusion of the 7,7-diphenylnorbornane (DPN) subunit. The inner cavity of 4 adopts a belt-shaped structure, while 6 has a twisted