Acyclic mononuclear and macrocyclic dinuclear silver(I) complexes of Schiff base ligands derived from N,N-bis(2-aminoalkyl)-2-phenylethylamines

✍ Scribed by David.E. Fenton; Paul C. Hellier

• Publisher: Elsevier Science
• Year: 1992
• Tongue: English
• Weight: 413 KB
• Volume: 198-200
• Category: Article
• ISSN: 0020-1693
• DOI: 10.1016/s0020-1693(00)92401-0

✦ Synopsis

The svnthesis and character&&on of acyclic mononuclear and macrocvclic dinuclear silverf1) comnlexes of liaands _,~~~~~._~_ ~~ , -~~~ ~-._ _ ~, ~~~_ _~~~~ ~___~~ ~~~.._~, ~_~~~r~~~ o--mm derived from the Schiff base condensation of N, N-bis(2-aminoalkyl)-2-phenylethylamines with 2,6_diacetylpyridine are reported and discussed. It is noted that changing the 2-aminoalkyl groups of the alkylamines from ethyl to n-propyl provides a change from an acyclic mononuclear silver(I) compound to a macrocyclic dinuclear silver(I) compound. --* I^^^ _ ___ \ * ^_^ I^_^ Perkin-Eimer w4 (zzu MHZ) or Bruker ~-ZXI (ZYJ MHz) spectrometers; 13C NMR spectra were obtained on a Bruker AM-250 (62.9 MHz) instrument. Electron *Author to whom correspondence should be addressed. impact (EI) and chemical impact (CI, ammonia) mass PV,PP+V., ,,,PVP ~_p,.nr~'=TI with ca lCrQtr\a hKC'X an~~+mm~+~r. 0pA4Ica W&SAY ICIWAUCIU WlLLI u IXLUC"~ I.I"bJ Yy~cLI"uIuLu) Q l=+-C 13 A?ol, lLT NMR iPl3Pl.i R-. 7.75