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A highly selective method for α-alkylation of ketones via potassium enoxytrialkylborates

✍ Scribed by Ei-ichi Negishi; Michael J. Idacavage; Frank DiPasquale; Augustine Silveira Jr.

Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
226 KB
Volume
20
Category
Article
ISSN
0040-4039

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✦ Synopsis

Despite numerous recent developments in the area of chemistry of enolates,' it still remains difficult, in many cases,to control regiochemistry, stereochemistry and the number of carbon-carbon bonds formed in the reaction of enolates with carbon electrophiles.

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