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Recyclable Palladium Catalyst for Highly Selective α Alkylation of Ketones with Alcohols.

✍ Scribed by Min Serk Kwon; Namdu Kim; Seong Hyeok Seo; In Soo Park; Ravi Kumar Cheedrala; Jaiwook Park

Publisher
John Wiley and Sons
Year
2006
Weight
31 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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A highly selective method for α-alkylati
A highly selective method for α-alkylation of ketones via potassium enoxytrialkylborates
✍ Ei-ichi Negishi; Michael J. Idacavage; Frank DiPasquale; Augustine Silveira Jr. 📂 Article 📅 1979 🏛 Elsevier Science 🌐 French ⚖ 226 KB

Despite numerous recent developments in the area of chemistry of enolates,' it still remains difficult, in many cases,to control regiochemistry, stereochemistry and the number of carbon-carbon bonds formed in the reaction of enolates with carbon electrophiles.