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A Highly Regio- and Stereoselective Formation of Bicyclo[4.2.0]oct-5-ene Derivatives Through Thermal Intramolecular [2 + 2] Cycloaddition of Allenes.

โœ Scribed by Hiroaki Ohno; Tsuyoshi Mizutani; Yoichi Kadoh; Akimasa Aso; Kumiko Miyamura; Nobutaka Fujii; Tetsuaki Tanaka


Publisher
John Wiley and Sons
Year
2007
Weight
45 KB
Volume
38
Category
Article
ISSN
0931-7597

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Highly Regio- and Stereoselective Iodohy
โœ Zhenhua Gu; Youqian Deng; Wei Shu; Shengming Ma ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 91 KB ๐Ÿ‘ 2 views

## Abstract An efficient protocol for the highly regioโ€ and stereoselective synthesis of 4โ€(3โ€ฒโ€hydroxyโ€2โ€ฒโ€iodoalkโ€1โ€ฒ(__Z__)โ€enyl)furanโ€2(5__H__)โ€one derivatives __via__ selective iodohydroxylation of nonโ€heteroatomโ€substituted allenes, i.e., 4โ€allenylโ€2(5__H__)furanones, has been developed. The reg