A highly efficient catalyst system for the isomerization of methyl formate to acetic acid
โ Scribed by David J. Schreck; David C. Busby; Richard W. Wegman
- Publisher
- Elsevier Science
- Year
- 1988
- Weight
- 334 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0304-5102
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๐ SIMILAR VOLUMES
Coordinate bonds form between oxygen and platinum atoms in crosslinked poly[(maleic acid)-co-styrene]-platinum complex according to FTIR and XPS measurements. The complex is demonstrated to be an active and selective catalyst for the hydrogenation of methyl formate under mild conditions (25"C, 1 atm
activation entropy and the minimal influence of solvent rule out an ionic mechanism. The reaction Id + 2b could proceed via bicyclic triazoIines["' or be interpreted as a hetero-Cope rearrangement'"'. Table I. Some physical data of the new compounds Id, 2b, 4a, 5, 6a, and 6b.