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Isomerization of methyl formate to acetic acid catalysed by the Ru(II)-Sn(II) heteronuclear cluster complex [Ru(SnCl3)5(PPh3)]3−

✍ Scribed by Takeshi Ohnishi; Toshihiro Suzuki; Tetsu Yamakawa; Sumio Shinoda

Publisher: Elsevier Science
Year: 1993
Weight: 437 KB
Volume: 84
Category: Article
ISSN: 0304-5102
DOI: 10.1016/0304-5102(93)80083-7

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## Catalytic activity of [ ( $-C5Hs) (PPh,),RuX] (X = Cl ( 1), SnF, (2) ) was investigated for the highly selective formation of methyl acetate with methanol used as the sole source. Complex 2 was found to be more catalytically active than the singlemetallic complex 1. For both complexes, the init