Acid catalyzed cope rearrangements of 2-
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William G. Dauben; André Chollet
📂
Article
📅
1981
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Elsevier Science
🌐
French
⚖ 227 KB
The Cope rearrangement of 1,5-dienes bearing acyl substituents in the 2-position of the diene system is strongly accelerated by protic and Lewis acids. Table 1. Rearrangement of 2-Acyl-1,5-dienes. Starting Material Acid Mol % Acid Conditionsa Productsb Isolated Yield !A CF3C02H 100 15 min, CH2C12 ,&