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Kinetics of the Cope rearrangement of a 3,4-diphenylhexa-1,5-diene

✍ Scribed by Lutz, Raymond P.; Berg, Harlan A. J.

Book ID
126135531
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
293 KB
Volume
45
Category
Article
ISSN
0022-3263

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## Abstract The classical rules for __Cope__ rearrangements predict a transition state with chair form to be favored over the boat form. On the other hand, bridged homotropylidenes, which allow only a boat‐form transition state by steric reasons, have extremely low barriers. A controversy about the