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Palladium dichloride catalyzed cope rearrangements of functionalized acyclic 1,5-dienes

✍ Scribed by Larry E Overman; Alfred F Renaldo

Book ID
108382466
Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
205 KB
Volume
24
Category
Article
ISSN
0040-4039

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The Cope rearrangement of 1,5-dienes bearing acyl substituents in the 2-position of the diene system is strongly accelerated by protic and Lewis acids. Table 1. Rearrangement of 2-Acyl-1,5-dienes. Starting Material Acid Mol % Acid Conditionsa Productsb Isolated Yield !A CF3C02H 100 15 min, CH2C12 ,&