A general method for the preparation of zirconocene complexes of substituted benzynes: in situ generation, coupling reactions, and use in the synthesis of polyfunctionalized aromatic compounds
โ Scribed by Buchwald, Stephen L.; Watson, Brett T.; Lum, Robert T.; Nugent, William A.
- Book ID
- 120828650
- Publisher
- American Chemical Society
- Year
- 1987
- Tongue
- English
- Weight
- 625 KB
- Volume
- 109
- Category
- Article
- ISSN
- 0002-7863
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## Abstract A new method for the __in situ__ generation of various Ti(III) complexes is presented. CyclohexadienylโTi(IV) derivatives, which are readily prepared from the corresponding lithiated cyclohexadienes, afford the corresponding Ti(III) complexes upon thermal C๏ฃฟTiโbond homolysis. The Ti(III