A general and concise asymmetric synthesis of sphingosine, safingol and phytosphingosines via tethered aminohydroxylation
β Scribed by Kumar, Pradeep; Dubey, Abhishek; Puranik, Vedavati G.
- Book ID
- 121260969
- Publisher
- Royal Society of Chemistry
- Year
- 2010
- Tongue
- English
- Weight
- 494 KB
- Volume
- 8
- Category
- Article
- ISSN
- 1477-0520
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## A Concise Asymmetric Synthesis of the Pheromone 1-Methylcyclohex-2-enol (IV) via a "Merged Substitution-Elimination Reaction". -The title compound (III) is prepared from cyclohexene (I) via Sharpless asymmetric dihydroxylation using AD-mix-Ξ², tosylation and an unexpected elimination reaction.