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ChemInform Abstract: A Concise Asymmetric Synthesis of the Pheromone 1-Methylcyclohex-2- enol (IV) via a “Merged Substitution-Elimination Reaction”.

✍ Scribed by D. P. G. HAMON; K. L. TUCK


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis


A

Concise Asymmetric Synthesis of the Pheromone 1-Methylcyclohex-2-enol (IV) via a "Merged Substitution-Elimination Reaction".

-The title compound (III) is prepared from cyclohexene (I) via Sharpless asymmetric dihydroxylation using AD-mix-β, tosylation and an unexpected elimination reaction. -(HAMON, D.


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