ChemInform Abstract: A Concise Asymmetric Synthesis of the Pheromone 1-Methylcyclohex-2- enol (IV) via a “Merged Substitution-Elimination Reaction”.
✍ Scribed by D. P. G. HAMON; K. L. TUCK
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
A
Concise Asymmetric Synthesis of the Pheromone 1-Methylcyclohex-2-enol (IV) via a "Merged Substitution-Elimination Reaction".
-The title compound (III) is prepared from cyclohexene (I) via Sharpless asymmetric dihydroxylation using AD-mix-β, tosylation and an unexpected elimination reaction. -(HAMON, D.
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