A Flexible Route to [4.1.1]Propellanes
✍ Scribed by Ahmad R Al Dulayymi; Juma'a R Al Dulayymi; Mark S Baird
- Book ID
- 104257879
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 542 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
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## Abstract The 1,7‐disubstituted tricyclo[4.1.0^2,7^]heptanes ^1a^ and b could be synthesized using Fe^III^‐catalyzed cross coupling methods. The reaction of LDA with 1a and 1b afforded an equilibrium mixture of the organolithium compounds 6 and 7, respectively. Whereas 6a/7a cyclized to the stabl
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## Abstract Durch Umsetzung von Tricyclo[4.1.0.0^2,7^]hept‐1‐yllithium (**1b**) mit Dichlorsilanen oder mit Siliciumtetrachlorid wurden silylsubstituierte Tricylco[4.1.0.0^2,7^]heptan‐Derivate **2**, **4** erhalten, die nach erneuter Metallierung der Bicyclo[1.1.0]butan‐Brückenkopfpositionen mit Di