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A Flexible Route to [4.1.1]Propellanes

✍ Scribed by Ahmad R. Al Dulayymi; Juma'a R. Al Dulayymi; Mark S. Baird

Book ID
104209822
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
255 KB
Volume
56
Category
Article
ISSN
0040-4020

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A Flexible Route to [4.1.1]Propellanes
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## Abstract The 1,7‐disubstituted tricyclo[4.1.0^2,7^]heptanes ^1a^ and b could be synthesized using Fe^III^‐catalyzed cross coupling methods. The reaction of LDA with 1a and 1b afforded an equilibrium mixture of the organolithium compounds 6 and 7, respectively. Whereas 6a/7a cyclized to the stabl

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## Abstract Durch Umsetzung von Tricyclo[4.1.0.0^2,7^]hept‐1‐yllithium (**1b**) mit Dichlorsilanen oder mit Siliciumtetrachlorid wurden silylsubstituierte Tricylco[4.1.0.0^2,7^]heptan‐Derivate **2**, **4** erhalten, die nach erneuter Metallierung der Bicyclo[1.1.0]butan‐Brückenkopfpositionen mit Di