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A flexible new synthetic route to daunomycinone, adriamycinone, and their 6-deoxy analogs

โœ Scribed by Boeckman, Robert K.; Cheon, Seung Hoon

Book ID
127190387
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
271 KB
Volume
105
Category
Article
ISSN
0002-7863

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+)-7-Deoxy-6-epicastanospermine 1, (-)-7,8-dideoxy-6-epicastanospermine 2 and (-)-Nacetylslaframine 4 have been synthesized via the stereoselective intramolecular iodocyclization of trichloroacetimidates generated from cis-olefinic allylic alcohols 7 and 15, respectively.