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A versatile synthetic route to indolizidines, (+)-7-deoxy-6-epicastanospermine, (−)-7,8-dideoxy-6-epicastanospermine and (−)-N-acetylslaframine

✍ Scribed by Sung Ho Kang; Joon Seop Kim; Joo-Hack Youn

Book ID: 104260228
Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 249 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)02051-6

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✦ Synopsis

+)-7-Deoxy-6-epicastanospermine 1, (-)-7,8-dideoxy-6-epicastanospermine 2 and (-)-Nacetylslaframine 4 have been synthesized via the stereoselective intramolecular iodocyclization of trichloroacetimidates generated from cis-olefinic allylic alcohols 7 and 15, respectively.

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