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A Facile Synthesis of 3-Aryl Pyroglutamic Acid. Facile Synthesis of Baclofen and Chlorpheg.

โœ Scribed by Meng-Yang Chang; Pei-Pei Sun; Shui-Tein Chen; Nein-Chen Chang

Publisher
John Wiley and Sons
Year
2003
Weight
110 KB
Volume
34
Category
Article
ISSN
0931-7597

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## Abstract Cyanoacetyldiazoindolโ€2โ€one (**__3__**), the condensation product of cyanoacetohydrazide with isatin (**__1__**), could be cyclized in acidic medium via its C๏ฃพN group and its enolic OH to give cyanomethyloxadiazoleโ€spiroindoline (**__4__**). The presence of the methylcyano side chain co