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A facile and selective oxidation of sulfides to sulfones

✍ Scribed by Waldemar Priebe; Grzegorz Grynkiewicz


Book ID
103407202
Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
277 KB
Volume
32
Category
Article
ISSN
0040-4039

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The binuclear MnlV-Mn Iv manganese complex lcatalyzes the periodic acid oxidation of sulfides to sulfones under mild conditions. The reaction was found to be highly selective giving almost quantitative yields of the sulfones even in the presence other easily oxidized groups. Only amines were found t