## Abstract **Taking the reins**: The title transformation of thioamides and __N__‐diphenylphosphinoyl imines is described. By harnessing the power of cooperative catalysis between a soft Lewis acid and a hard Brønsted base, thioamide carbon pronucleophiles can furnish Mannich products (see scheme)
✦ LIBER ✦
A Direct Catalytic Asymmetric Mannich-Type Reaction to syn-Amino Alcohols.
✍ Scribed by Barry M. Trost; Lamont R. Terrell
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 43 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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