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A direct carbon-13 and nitrogen-15 nmr study of europium(iii)-isothiocyanate complex formation in aqueous solvent mixtures

✍ Scribed by A. Fratiello; V. Kubo-Anderson; E. Bolanos; J. V. Ortega; R. D. Perrigan; L. Saenz; S. M. Stoll; K. Wong


Book ID
110677352
Publisher
Springer US
Year
1997
Tongue
English
Weight
854 KB
Volume
26
Category
Article
ISSN
0095-9782

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A direct, low-temperature hydrogen-1, nitrogen-15, and yttrium-89 NMR study of inner-shell complex formation between yttrium(III) and isothiocyanate ion in aqueous solvent mixtures has been completed. At -105 to \(-115^{\circ} \mathrm{C}\) in water-acetoneFreon 12 mixtures, ligand exchange is slow e