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A Direct Carbon-13 and Nitrogen-15 NMR Study of Cerium(III)–Isothiocyanate Complexation in Aqueous Solvent Mixtures

✍ Scribed by Anthony Fratiello; Vicki Kubo-Anderson; Deborah J. Lee; Richard D. Perrigan; Kenneth Wong


Book ID
110410951
Publisher
Springer US
Year
1999
Tongue
English
Weight
887 KB
Volume
28
Category
Article
ISSN
0095-9782

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A direct, low-temperature hydrogen-1, nitrogen-15, and yttrium-89 NMR study of inner-shell complex formation between yttrium(III) and isothiocyanate ion in aqueous solvent mixtures has been completed. At -105 to \(-115^{\circ} \mathrm{C}\) in water-acetoneFreon 12 mixtures, ligand exchange is slow e