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A direct hydrogen-1, carbon-13, and nitrogen-15 NMR study of lutetium(III)-isothiocyanate complexation in aqueous solvent mixtures

โœ Scribed by A. Fratiello; V. Kubo-Anderson; E. Bolanos; R. D. Perrigan; L. Saenz; S. M. Stoll


Publisher
Springer US
Year
1996
Tongue
English
Weight
621 KB
Volume
25
Category
Article
ISSN
0095-9782

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A direct, low-temperature hydrogen-1, nitrogen-15, and yttrium-89 NMR study of inner-shell complex formation between yttrium(III) and isothiocyanate ion in aqueous solvent mixtures has been completed. At -105 to \(-115^{\circ} \mathrm{C}\) in water-acetoneFreon 12 mixtures, ligand exchange is slow e