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A diastereoselective synthesis of (1SR,3SR,7RS)-3-methyl-α-himachalene, the sex pheromone of the sandfly, Lutzomyia longipalpis (Diptera: Psychodidae)

✍ Scribed by Samuel Dufour; Pascalie Castets; John A. Pickett; Antony M. Hooper

Book ID: 113929459
Publisher: Elsevier Science
Year: 2012
Tongue: French
Weight: 301 KB
Volume: 68
Category: Article
ISSN: 0040-4020
DOI: 10.1016/j.tet.2012.04.037

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1S,3S,7R)-3-Methyl-a-himachalene, the sex pheromone of the male sand¯y (Lutzomyia longipalpis) from Jacobina, Brazil, was synthesized enantioselectively by employing Evans' or Oppolzer's asymmetric methylation as the key step. The absolute con®guration at the ring junction of this pheromone is oppos

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