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A Convenient Synthesis of (E)-β-Hydroxyvinyl Trimethylsilanes via 3,3-bis(Trimethylsilyl)propene

✍ Scribed by Princet, Bruno; Anselme, Gilles; Pornet, Jacques

Book ID
126525722
Publisher
Taylor and Francis Group
Year
1999
Tongue
English
Weight
515 KB
Volume
29
Category
Article
ISSN
0039-7911

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📜 SIMILAR VOLUMES

The tetrahydropyranyl ether of (E)-3-bro
The tetrahydropyranyl ether of (E)-3-bromo-3-trimethylsilyl-2-propen-1-ol, a single synthon for the (E)-β-formylvinyl anion and cation
✍ R.Bryan Miller; Mohammed I. Al-Hassan 📂 Article 📅 1983 🏛 Elsevier Science 🌐 French ⚖ 224 KB

The tetrahydropyranyl ether of (E)-3-bromo-3-trimethylsilyl-2-propen-l-01 can serve as a single synthon for both the (E)-B-formylvinyl anion and cation depending upon the manner in which the bromine group is stereospecifically replaced by an alkyl group. mmol, 80% yield) of colorless product. GLC a