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A stereocontrolled synthesis of Z and E terminal dienes from pinacol E-1-trimethylsilyl-1-propene-3-boronate

โœ Scribed by David Jieh Shyh Tsai; Donald S. Matteson


Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
136 KB
Volume
22
Category
Article
ISSN
0040-4039

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Stereospecific synthesis of (1E,3Z)- and
โœ V. Fiandanese; G. Marchese; G. Mascolo; F. Naso; L. Ronzini ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 264 KB

A new synthesis of stereodefined 1-trimeUlylsllyl-1,3-dlenes is described. The method is based on two sequential coupling reactions between Grlgnard reagents and the readily available (Z)-or (15)-l -bromo-2-phenylthloethene, In the presence of transition metal catalysts.